I am seeing 7.32% 5v5 and ~9.5% on the PP.
Edit: Ohh you mean 10.22% of shots go in while he is on the ice. Not he shoots at 10.22%. Honestly, a PDO of 101.4 isn't an outlier. Slightly lucky. But close enough to the mean.
From where? Not hockeyanalysis http://stats.hockeyanalysis.com/ratings.php?disp=1&db=201516&sit=5v5&pos=skaters&minutes=500&teamid=25&type=shots&sort=ShPct&sortdir=DESC