For recent years, you have goals against per 60 minutes (GA/60). But quality of competition needs to be taken into account, and while there have been attempts to quantify this, I don't find them very satisfactory.
Overpass's adjusted plus/minus is a useful tool for comparing players in similar situations. (He can explain what it is more thoroughly).
Percentage of time spent on the penalty kill, combined with a good penalty kill % would indicate a good penalty killer.
One thing that i think is useful is to compare Norris voting and All-Star voting with points production. If a player gets a higher share of votes than his point production would indicate, that means something. Likewise if someone like Phil Housley racks up a lot of point, but with disproportionately lower share of Norris votes, that means something too.
And it's not so much a stat, but there is a stickied threat on this board that has coach's polls from over the years - one of the categories in these coach's polls is often "best defensive defenseman."