I'm not sure it's a predictive stat, but it sure seems to be a descriptive stat.
Last night, Wild got killed. Just terrible. In every sense of the word. They gave up a breakaway first shift of the game and LA scored. Then they gave up a 3-on-1 two shifts later and LA scored. Lots of turnovers and crappy shots from the perimeter.
PDO was 786, shot differential +9. Can't really tell anything from Corsi because LA scored on their first two shots and Wild never scored.
But if you look at the PDO, you think, wow the Wild were terribly unlucky. You watch the game, probably their worst game of the year.
Not to be a dick - and I mean that sincerely - but the problem with your interpretation is that it's contradicted by all of the available evidence.
For example, quite a few bloggers counted scoring chances for a variety of teams over the 2010-11 NHL season. I happened to have collected data from all games for which scoring chances were counted. It turns out that there was scoring chances data for 386 out of the 1230 games played that year, which isn't bad.
For that 386 game sample, I took the trouble of calculating each team's:
1. Scoring Chance Ratio
2. Fenwick Ratio
3. Corsi Ratio
4. PDO Number
The correlation between Scoring Chance Ratio and Fenwick Ratio was substantial, at 0.82. The correlation between Scoring Chance Ratio and Corsi Ratio was high as well, although somewhat less so, at 0.69.
The correlation between PDO Number and Scoring Chance Ratio, however, was negative 0.37. If PDO was reflective of how well a team was playing, we would have expected to obtain a significant positive correlation, like with Fenwick and Corsi. But we didn't.
This result is actually not too surprising, given that the majority of variation in PDO at the team level over the course of a single season is due to luck. If a majority of the variation in a statistic is explained by luck, it, by definition, is unlikely to be correlated with measures of ability. So one would expect PDO to be uncorrelated with measures of team ability, such as scoring chance ratio.
This is actually susceptible to precise calculation - if you look at data from the 2007-08 to 2010-11 NHL seasons, it appears that variation in PDO at the team level is 69.6% luck, 30.4% skill.
If you expand the sample to include the 2003-04 to 2006-07 NHL seasons, the skill component increases to 39.1%, but the majority of the variation from team to team is still explained by luck.
All of this is not to say that PDO is entirely a reflection of luck - it's not, and the above data bears that out. Some teams will sustainably do better than others with respect to PDO over large samples.
It's simply that when we're talking about 20, 30, or 40 game samples, or even an entire regular season, the noise tends to dominate the signal.