There is no catch-all defensive stat. You can use several stats to put together a good picture though.
CF% and Rel.CF%
xGF% and Rel.xGF%
Over a large sample, GF% and rel.GF% can give you a good idea of performance, but very little predictive value
CA/60 and Rel
SA/60 and Rel
xGF/60 and Rel
Then you want to look at zone start percentage, QoT and QoC for the context of how they're used and against whom.
And I guess takeaways, blocked shots (hits?) etc as well.
Those aren't particularly useful for measuring impact. Typically they just mean the other team has the puck more when the defender in question is on the ice.
Contextually there are exceptions, like when defenders are getting dungeon dzone starts against top 6 competition game-after-game-after-game, but for the most part if you have a lot of blocked shots, that just means you're bad at puck retrieval and exiting the zone successfully.